application of molybdophosphoric acid as reducing agent/ stabilizer in the synthesis of gold nanoparticles under uv irradiation

نویسندگان

a. ayati

a. ahmadpour

f. f. bamoharram

m. m . heravi

h. rashidi

چکیده

in this paper, we have described the size-controlled synthesis of gold nanoparticles based on the reduction of au3+ (haucl4 ) using molybdophosphoric acid (h3[pmo12o40 ], hpmo) under uv-irradiation. in the process, hpmo plays the role of photocatalyst, reducing agent and stabilizer and propan-2-ol acts as a sacrificial agent. this method allows the synthesis of uniform hexagonal nanoparticles with an average size that is tunable between 1.93 and 119 nm by varying the gold ion concentration, hpmo dose (or molar ratio of gold ion to hpmo) and propan-2-ol amount. we have found that there is a critical ratio for [au3+]/[hpmo], in which two opposing trends in the size of gold nanoparticles would happened.

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عنوان ژورنال:
international journal of nanoscience and nanotechnology

ناشر: iranian nano society

ISSN 1735-7004

دوره 7

شماره 2 2011

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